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The archetypal example is the injection of concentrated nanoscale zero-valent iron (nZVI) slurries (often in the g L1 range) into groundwater plumes to form permeable reactive barriers.67,70 This scenario creates a localised, high-concentration hotspot where the fate of the relatively pristine, as-synthesised ENMs is initially dominated by the immediate, and often aggressive, geochemistry of the subsurface environment